个人简介:柴国利,女,博士,硕士生导师,E-mail:guolichai@126.com
教育经历:
2007.09-2011.06信阳师范学院 化学化工学院,化学教育专业,理学学士;
2011.09-2014.06大连理工大学 化学化工学院,应用化学专业,工学硕士;
2014.09-2017.12中国科学院上海有机化学研究所,有机化学专业,理学博士。
工作经历:
2018.01-现在 化学化工学院 有机化学研究所 讲师。
研究领域与兴趣:
1、功能有机分子的设计与合成;
2、不对称催化;
近年来主持的主要科研项目:
1、河南省自然科学基金-青年科学基金项目(232300421371,2023.01-2024.12)
2、河南省高等学校重点科研项目(21A150028,2021.01-2022.12)
3、国家级科研项目培育基金-青年培育(2020PL20, 2020.01-2022.12)
4、博士科研启动课题(qd18005, 2019.01-2021.09)
代表性论文:
1、Xiao Wang,Guo-Li Chai,*Ya-Jing Hou, Ming-Qian Zhou, Junbiao Chang.* Enantioselective Synthesis of Chiral Organosilicon Compounds by Organocatalytic Asymmetric Conjugate Addition of Boronic Acids to β‑Silyl-α,β-Unsaturated Ketones.J. Org. Chem.2023,88(5), 3254–3265.
2、Guo-Li Chai,*# En-Ze Yao,# Rui-Hao Liu, Junbiao Chang.* Chiral-Boron-Complex-Catalyzed Asymmetric [3 + 2] Cycloaddition of 2′-Hydroxychalcones withN,N′‑Cyclic Azomethine Imines.Org. Lett.2022,24(35), 6449–6454.
3、Guo-Li Chai,*Ping Zhang, En-Ze Yao, Junbiao Chang.*Enantioselective Conjugate Addition of Boronic Acids to α,β-Unsaturated 2-Acyl Imidazoles Catalyzed by Chiral Diols.J. Org. Chem.2022,87(14), 9197–9209.
4、En-Ze Yao,Guo-Li Chai,*Ping Zhang, Bo Zhu, Junbiao Chang.*Chiral dihydroxytetraphenylene-catalyzed enantioselective conjugate addition of boronic acids to β-enaminones.Org. Chem. Front.2022,9(9), 2375–2381.
5、Lu Zhao,#En-Ze Yao,#Guo-Li Chai,* Shi-Yu Ma, Junbiao Chang.*Organocatalyzed Enantioselective Conjugate Addition of Boronic Acids to β,γ-Unsaturated α-Ketoesters.J. Org. Chem.2021,86(24), 18211–18223.
6、Ping Zhang,Guo-Li Chai,* En-Ze Yao, Li-Xiao Guo, Xue-Yu Liu, Junbiao Chang.*Asymmetric Double-Conjugate Addition of Alkenylboronic Acids to Dienones Catalyzed by Chiral Diols.Org. Chem. Front.2021,8(7), 1575–1580.
7、Guo-Li Chai,* Yan Qiao, Ping Zhang, Rong Guo, Juan Wang, Junbiao Chang.*Chiral Hydroxytetraphenylene-Boron Complex-Catalyzed Asymmetric Diels-Alder Cycloadditionof 2'-Hydroxychalcones.Org. Lett.2020,22(20), 8023–8027.
8、Guo-Li Chai,* A-Qiang Sun, Dong Zhai, Juan Wang, Wei-Qiao Deng, Henry N. C. Wong, Junbiao Chang. Chiral Hydroxytetraphenylene-Catalyzed Asymmetric Conjugate Addition of Boronic Acids to Enones.Org. Lett.2019,21(13), 5040–5045.
9、Guo-Li Chai, Bo Zhu, Junbiao Chang.* Synthesis and Application of Substituted 1,16-Dihydroxytetraphenylenes in Catalytic Asymmetric Allylboration of Ketones.J. Org. Chem.2019,84(1), 120–127.
10、Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong.*Asymmetric Darzens Reaction of Isatins with Diazoacetamides Catalyzed by Chiral BINOL-Titanium Complex.J. Org. Chem.2017,82(23), 12647–12654.
11、Guo-Li Chai, Jian-Wei Han, Henry N. C. Wong.* Hydroxytetraphenylenes as Chiral Ligands: Application to Asymmetric Darzens Reaction of Diazoacetamide with Aldehydes.Synthesis2017,49(1), 181–187.