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刘统信 博士，副教授，硕士生导师 河南省教育厅学术带头人 河南省高校科技创新人才 青年骨干教师 Email:liutongxin@htu.edu.cnandliutongxin_0912@126.com |
教育与研究经历： 2017年1月—至今 化学化工学院 副教授 2012年8月—2016年12月 化学化工学院 讲师 2007年9月—2012年6月 中国科学技术大学 化学与材料科学学院 理学博士 2005年9月—2007年6月山东师范大学 化学化工与材料科学学院 理学学士 研究领域与兴趣：富勒烯化学，绿色有机合成化学，金属有机化学 近年来主持的主要科研项目: 1. 新型开孔富勒烯的设计、合成与光伏性能研究，国家自然科学基金 (U1904181) 2. 河南省高校科技创新人才支持计划 (18HASTIT006) 3. 富勒烯氮杂衍生物合成，中国博士后科学基金特别资助 (2015T80769) 4. 新型富勒烯含氮杂环化合物的合成及其衍生化研究，国家自然科学基金 (21302044) 5. 新型富勒烯碳杂稠环衍生物材料的合成与性能研究，国家自然科学基金 (U1304524) 6. 利用串联反应构建新型杂环富勒烯衍生物研究，中国博士后科学基金面上资助 (2013M530339) 7.芳基酰胺化合物在构建结构多样性富勒烯衍生物中的应用，优秀青年科学基金 (14YQ004) 代表性论文： 27.Tong-Xin Liu,* Xin Wang, Shilu Xia, Muqing Chen,* Mingjie Li, Panting Yang, Nana Ma, Ziqi Hu, Shangfeng Yang,*GuishengZhang,* and Guan-Wu Wang*, Dearomative Ring-Fused Azafulleroidsand Carbazole -Derived Metallofullerenes: ReactivityDictated by Encapsulation in a Fullerene Cage Angew. Chem. Int. Ed.,2023,62, e202313074 • Highlighted by X-MOL •Highlighted by CBGNews
26.Di Chao,Tong-Xin Liu,* Pengling Zhang, Shilu Xia, and Guisheng Zhang*,Copper-Mediated Radical-Induced Ring-Opening RelayCascadeCarboannulation Reaction of [60]Fullerene with CyclobutanoneOxime Esters:Access to[60]Fullerene-Fused Cyclopentanes J. Org. Chem.,2023,88, 13076-13088.
25.Tong-Xin Liu,*Pangting Yang, Nana Ma,Xiaojun Li,Xin Wang,Jinliang Ma,and Guisheng Zhang*,Synthesis of [60]Fullerene-Fused Allylbenzofurans via Palladium-Catalyzed Migration Reaction Chin. J. Chem.,2023,41,1733-1739. • Invitation for a Special Issue on Recent Advances in Fullerene Chemistry • Selected as theInside Back Cover
24.Tong-Xin Liu,*Xin Wang, Pengling Zhang, Panting Yang, Xiaojun Li, and Guisheng Zhang*,Assembly of Diverse [60]Fullerene-Fused Tricyclic Scaffolds via aPalladium-Catalyzed Cascade [2 + 2 + 2] Annulation Reaction Org. Lett.,2022,24,9102-9106.
23.Tong-Xin Liu,*Chuanjie Zhang, Pengling Zhang, Xin Wang, Jinliang Ma, andGuisheng Zhang*,Palladium-catalyzed decarboxylative [2 + 3]cyclocarbonylation reactions of [60]fullerene:selective synthesis of [60]fullerene-fused3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes Org. Chem. Front.,2022,9, 5564-5570.
22.Tong-Xin Liu,*Xue Zhu, Shilu Xia, Xin Wang, Pengling Zhang, and Guisheng Zhang*,NHC-Catalyzed Three-Component Hydroalkylation Reactions of[60]Fullerene: An Umpolung Approach to Diverse MonoalkylatedHydrofullerenes Org. Lett.,2022,24, 3691-3695. • Highlighted by Synfacts,2022,18, 0857. • Highlighted by CBGNews
21.Tong-Xin Liu,*Han Wu,Nana Ma, Chuanjie Zhang, Pengling Zhang, Jinliang Ma,and Guisheng Zhang*,Acid-Responsive Dissociation of Ferrocene Compounds: Diels−AlderDiene Equivalents for Selective Preparation of [60]Fullerene-FusedBicyclo[2.2.1]hept-5-enes J. Org. Chem.,2022,87, 3104-3113.
20.Jinliang Ma,Tong-Xin Liu,*Pengling Zhang, Xuna Zhao and Guisheng Zhang*,Metal-Free-Catalyzed Three-Component [2+2+2] Annulation Reaction of [60]Fullerene, Ketones, and Indoles: Access to Diverse [60]Fullerene-Fused 1,2-Tetrahydrocarbazoles Org. Lett.,2021,23, 1775-1781.
19.Jinliang Ma,Tong-Xin Liu,*Pengling Zhang, Chuanjie Zhang and Guisheng Zhang*,Palladium-catalyzed domino spirocyclization of [60]fullerene: synthesis of diverse [60]fullerene-fused spiro[4,5]/[5,5] derivatives Chem. Commun.,2021,57, 49-52. • Selected as the Inside Front Cover • Highlighted by X-MOL • Highlighted by RSC China
18. Conghui Wu,Tong-Xin Liu,*Pengling Zhang, Xue Zhu, and Guisheng Zhang*,Iron-Catalyzed Redox-Neutral Radical Cascade Reaction of [60]Fullerene with γ,δ-Unsaturated Oxime Esters: Preparation of Free (N–H) Pyrrolidino[2¢,3¢:1,2]fullerenes Org. Lett.,2020,22,7327-7332. • Highlighted by CBG News
17.Qingfeng Liu,Tong-Xin Liu,*Jinliang Ma, and Guisheng Zhang*,Palladium-Catalyzed Three-Component Tandem Coupling−Carboannulation Reaction Leading to Polysubstituted [60]Fullerene-Fused Cyclopentanes Org. Lett.,2020,22, 284-289. • Highlighted by CBG News
16.Qingfeng Liu,Tong-Xin Liu,*Yifei Ru, Xue Zhu, and Guisheng Zhang*, Palladium-catalyzed decarboxylative heterocyclizations of [60]fullerene: preparation of novel vinyl-substituted [60]fullerene-fused tetrahydrofuran s/pyrans/quinolones Chem. Commun.,2019,55, 14498-14501.
15.Tong-Xin Liu,* Juan Wei, Pengling Zhang,* Yifei Ru, Jinliang Ma, Xingjie Zhang, Nana Ma, and Guisheng Zhang*, Copper-Catalyzed N−H/C−H Sequential Relay Oxidative Radical Carboannulation: Construction of Diversely Substituted [60]Fullerene-Fused Tetrahydrocyclopenta[b]indoles Org. Lett.,2019,21, 6461-6465. • Highlighted by CBG News
14.Qingfeng Liu,Tong-Xin Liu,*Nana Ma, Chenhao Tu, Ruoya Wang, and Guisheng Zhang*, Cu(II)/Mn(III)-Promoted Synergistic Radical N‑Heteroannulation Reaction: Synthesis of [60]Fullerene-Fused Tetrahydroquinoline Derivatives J. Org. Chem.,2019,84, 7255-7264.
13.Tong-Xin Liu,*Shuaishuai Yue, Changgeng Wei, Nana Ma,*Pengling Zhang, Qingfeng Liu, and Guisheng Zhang*, Solvent-promoted catalyst-free regioselective N-incorporation multicomponent domino reaction: rapid assembly ofπ-functionalized [60]fullerene-fused dihydrocarbolines Chem. Commun.,2018,54, 13331-13334. • Selected as the Outside Front Cover
12. Beibei Hu,Tong-Xin Liu,*Pengling Zhang, Qingfeng Liu, Jingjing Bi, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*, N‑Heterocyclic Carbene-Catalyzed α,β-Unsaturated Aldehyde Umpolung in Fullerene Chemistry: Construction of [60]Fullerene-Fused Cyclopentan-1-ones and Cyclohex-2-en-1-ones Org. Lett.,2018,20,4801-4805. • Highlighted by Synfacts,2018,14, 1303. • Highlighted by CBGNews
11.Tong-Xin Liu,*Shaoshuai Hua, Nana Ma, Pengling Zhang, Jingjing Bi, Zhiguo Zhang, and Guisheng Zhang*. Reactivity and Synthetic Applications of a-Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and Mono- and Disubstituted 1-Fulleropyrrolines via Copper-Catalyzed Redox-Neutral N-Heteroannulation with [60]Fullerene Adv. Synth. Catal.,2018,360, 142-152.
10. Shilu Xia,Tong-Xin Liu,*Pengling Zhang, Jinliang Ma, Qingfeng Liu, Nana Ma, Zhiguo Zhang, and Guisheng Zhang*. Broad Synthesis of Disubstituted Dihydrofuran-Fused [60]Fullerene Derivatives via Cu(I)/Ag(I)-Mediated Synergistic Annulation Reaction J. Org. Chem.,2018,83, 862-870. • Highlighted bySynfacts,2018,14, 0369.
9. Di Chao,Tong-Xin Liu,*Nana Ma, Pengling Zhang, Zheng Fu, Jinliang Ma, Qingfeng Liu, Fengjin Zhang, Zhiguo Zhang and Guisheng Zhang*. Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles Chem. Commun.,2016,52, 982-985.
8.Tong-Xin Liu,*Jinliang Ma, Di Chao, Pengling Zhang, Nana Ma, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*. Synthesis of C60-Fused Tetrahydrocarbazole/Dibenzothiophene/ Benzothiophene and Dibenzofuran Derivatives via Metal-Free Oxidative Dehydrogenative Carboannulation Org. Lett.,2016,18,4044-4047.
7.Tong-Xin Liu,*Jinliang Ma, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang and Guisheng Zhang*. AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene Chem. Commun.,2015,51, 12775-12778.
6.Tong-Xin Liu,*Zhenbei Zhang, Qingfeng Liu, Pengling Zhang, Penghao Jia, Zhiguo Zhang, and Guisheng Zhang*. Synthesis of [60]Fullerene-Fused Tetrahydroazepinones and Azepinonimines via Cu(OAc)2-Promoted N-Heteroannulation Reaction Org. Lett.,2014,16,1020-1023.
5.Tong-Xin Liu,*Yuquan Liu, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*. Iron-Mediated Internal-Oxidant Relay Cascade Reaction: Strategy to Synthesize Fullerenooxazoles and Hydroxyfullerenyl Amides J. Org. Chem.,2014,79, 11084-11090.
4.Tong-Xin Liu, Fa-Bao Li, Dian-Bing Zhou, and Guan-Wu Wang*. Ferric Perchlorate Promoted Reaction of [60]Fullerene with N−Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines J. Org. Chem.,2015,80, 11986-11992.
3.Tong-Xin Liu, Tao Wei, San-E Zhu, Guan-Wu Wang*, Mingzhi Jiao, Shangfeng Yang*, Faye L. Bowles, Marilyn M. Olmstead*, and Alan L. Balch*. Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids ofSc3N@Ih-C80 J. Am. Chem. Soc.,2012,134, 11956-11959.
2.Tong-Xin Liu, Fa-Bao Li, and Guan-Wu Wang*. Synthesis of [60]Fullerene-Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride Org. Lett.,2011,13,6130-6133.
1. Guan-Wu Wang,*Tong-Xin Liu, Mingzhi Jiao, Nan Wang, San-E Zhu, Chuanbao Chen, Shangfeng Yang*, Faye L. Bowles, Dr. Christine M. Beavers, Marilyn M. Olmstead*, Brandon Q. Mercado, and Alan L. Balch*. The Cycloaddition Reaction ofIh-Sc3N@C80with 2-Amino-4,5- diisopropoxybenzoic Acid and Isoamyl Nitrite to Produce an Open-Cage Metallofullerene, Angew. Chem., Int. Ed.,2011,50,4658-4662.
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