张凯歌 女,重点学科秘书,博士,副教授,硕士生导师,1986年3月出生,河南禹州人。主要从事新型分离介质在复杂体系(环境、食品和生物)中的应用研究。主持国家自然科学基金、中国博士后科学基金、河南省重点科技攻关、“i科普”科技志愿服务和河南省高等学校重点科研等项目8项;在Nanoscale, Trends in Analytical Chemistry, Food chemistry, Journal of Chromatography A, Talanta, Microchimica Acta等国内外学术期刊上发表论文20余篇;授权发明专利4件。1次参加国际会议并作口头报告。
受教育经历(:
2011/09-2015/06,中山大学,化学与化学工程学院,分析化学专业,博士
2008/09-2011/06,河南工业大学,化学与化学工程学院,分析化学专业,硕士
2004/09-2008/06,信阳师范学院,化学与化学工程学院,理学学士
环境分析、功能分离介质研制
主持的科研项目:
1. 国家自然科学基金青年科学基金项目,磁性分子印迹表面增强拉曼活性基底的研制及其在痕量环境污染物快检中的应用 (21605040),2017/01-2019/12,20万
2. 河南省重点科技攻关项目, 聚合低共熔溶剂功能化磁性纳米材料对黄河流域水体抗生素类PPCPs的分离富集及去除 (212102310533),2021/01-2022/12
3. 中国博士后科学基金项目,功能化磁性拉曼活性基底的研制及其在环境分析中的应用 (2016M592295),2016/01-2017/12,5万
4. 河南省高等学校重点科研项目,聚合低共熔溶剂功能化磁性纳米材料在环境水体紫外吸收剂分离富集中的应用 (22A610005), 2022/01-2023/12,5万元
5. “i科普”科技志愿服务项目,科普进校园,智慧新生活,2020/01-2020/12,3万
6. 河南省高等学校重点科研项目,功能化磁性SERS活性基底的研制及其在环境污染物检测中的应用 (16A610003),2016/01-2017/12,5万
7. 博士科研启动项目,功能化磁性SERS活性基底的研制及其在环境污染物检测中的应用 (51012190110),2016/01-2018/12,8万
8. 博士后科研启动项目,磁性复合纳米活性基底研制及表面增强拉曼光谱应用 (51012190010),2016/01-2017/12,3万
参加的科研项目:
1. 国家自然科学基金面上项目,分子印迹-金属有机骨架复合材料的可控构建及其对环境激素和抗生素的分离富集 (21876045),2019/01-2022/12,65万元
2. 国家自然科学基青年科学基金项目,基于零背景和多元信号放大的新型核酸生物传感器的构建及其对癌症标记物的高灵敏检测 (21705034),2018/01- 2020/12,25万元
3. 国家重大科学仪器设备开发项目,等离激元增强拉曼光谱仪器研发与应用 (2011YQ03012409)-任务9,2011/10-2015/09,615万
4. 国家自然科学基金面上项目,水体中激素类PPCPs原位富集、表面增强拉曼光谱快速检测新方法及其应用研究 (21277176),2013/01-2016/12,80万
5. 国家自然科学基金面上项目,循环动态在线分析系统研制与应用研究 (21475153),2015/01-2018/12,100 万
6. 国家基金委仪器专项,复杂体系多功能在线样品前处理联用系统的研制 (21127008),2012/01-2015/12,280万
代表性论文:
1. Zhang Kaige*, Guo Rong, Wang Yunhe, Nie Qiujun, Zhu Guifen*. One-step derivatization and temperature-controlled vortex-assisted liquid-liquid microextraction based on the solidification of floating deep eutectic solvents coupled to UV-Vis spectrophotometry for the rapid determination of total iron in water and food samples, Food Chemistry, 2022, 384: 132414.
2. Zhang Kaige*, Wang Yunhe, Li Shuangying, Zhu Guifen*. Air-assisted liquid-liquid microextraction based on the solidification of floating deep eutectic solvents for the simultaneous determination of bisphenols and polycyclic aromatic hydrocarbons in tea infusions via HPLC, Food Chemistry, 2021, 348: 129106.
3. Zhang Kaige*, Li Shuangying, Wang Yunhe, Fan Jing, Zhu Guifen*. Air-assisted liquid-liquid microextraction based on solidification of floating deep eutectic solvent for the analysis of ultraviolet filters in water samples by high performance liquid chromatography with the aid of response surface methodology. Journal of Chromatography A, 2020, 1618: 460876.
4. Zhang Kaige*, Liu Chuang, Li Shuangying, Wang Yunhe, Zhu Guifen, Fan Jing*. Vortex-assisted liquid-liquid microextraction based on a hydrophobic deep eutectic solvent for the highly efficient determination of Sudan I in food samples. Analytical Letters, 2020, 53: 1204-1217.
5. Cheng Guohao, Yu Wenna, Yang Can, Li Shiying, Wang Xiaoyue, Wang Peiyun, Zhang Kaige*, Li Xiang, Zhu Guifen*. Highly selective removal of 2,4-dinitrophenol by a surface imprinted sol-gel polymer. Journal of Applied Polymer Science, 2020, 137: 49236.
6. Zhang Kaige, Liu Chuang, Li Shuangying, Fan Jing*. A hydrophobic deep eutectic solvent based vortex-assisted liquid-liquid microextraction for the determination of formaldehyde from biological and indoor air samples by high performance liquid chromatography. Journal of Chromatography A, 2019, 1589: 39-46.
7. Zhu Guifen*, Li Wanwan, Wang Peiyun, Cheng Guohao, Chen Letian, Zhang Kaige*, Li Xiang. One-step polymerization of hydrophilic ionic liquid imprinted polymer in water for selective separation and detection of levofloxacin from environmental matrices. Journal of Separation Science, 2019, 43: 639-647.
8. Zhang Kaige*, Li Shuangying, Liu Chuang, Wang Qi, Wang Yunhe, Fan Jing*. A hydrophobic deep eutectic solvent-based vortex-assisted dispersive liquid-liquid microextraction combined with HPLC for the determination of nitrite in water and biological samples. Journal of Separation Science, 2018, 42: 574-581.
9. 张凯歌*, 王云鹤, 李双莹, 樊静*. 二苯碳酰二肼光度法测定铬(VI)不足及改进. 化学教育, 2019, 40: 49-52.
10. Zhang kaige, Hu yuling*, Li gongke*. In situ loading of very-dispersed silver nanoparticles on nanocrystalline magnesium oxide for real-time monitoring of catalytical reactions by surface enhancement Raman spectroscopy. Nanoscale, 2015, 7: 16952-16959.
11. Zhang Kaige, Yao Su, Li Gongke*, Yuling Hu*.One-step sonoelectrochemical fabrication of gold nanoparticles/carbon nanosheet hybrids for efficient surface-enhanced Raman scattering. Nanoscale, 2015, 7: 2659-2666.
12. Zhang Kaige, Liang Lizhen, Huang Meiying, Hu Yuling*, Li Gongke*. Determination of iodate in iodized salt and water samples by shell-isolated nanoparticle-enhanced Raman spectroscopy. Microchimica Acta, 2014, 181: 1301-1308.
13. Zhang Kaige, Hu Yuling*, Li Gongke*. Diazotization-coupling reaction-based selective determination of nitirte in complex samples using shell-isolated nanoparticle-enhanced Raman spectroscopy. Talanta, 2013, 116: 712-718.
14. He Lijun*, Zhang Kaige, Luo Xianli, Wang Caijuan, Zhang Shusheng. Effective indirect enrichment and determination of nitrite ion in water and biological samples using ionic liquid-dispersive liquid-liquid microextraction combined with high-performance liquid chromatography. Journal of Chromatography A, 2011, 1218: 3595-3600.
15. Hu Yuling*, Pan Jialiang, Zhang Kaige, Lian Haixian, Li Gongke*. Novel applications of molecularly-imprinted polymers in sample preparation. Trends in Analytical Chemistry, 2013, 43: 37-52.
16. 张凯歌, 胡玉玲*, 胡玉斐, 李攻科*. 分子印迹微萃取技术的研究进展. 色谱, 2012, 12: 1220-1228. (核心期刊)
17. 张凯歌, 何丽君*. 基于 [HMIM][Tf2N] 的分散液液微萃取氨基甲酸酯. 西北大学学报 (自然科学版), 2010, 40: 101-102.
授权专利成果:
1. 张凯歌, 樊静, 刘闯, 李双莹, 杜亭如, 赵扬扬. 疏水性低共熔溶剂涡旋辅助分散液液微萃取-高效液相色谱法检测甲醛的方法, 2020-11-6, 中国, ZL201810671110 .9
2. 张凯歌, 樊静; 刘闯; 李双莹; 赵扬扬; 杜亭如 ; 疏水性低共熔溶剂涡旋辅助分散液液微萃取-高效液相色谱法检测苏丹红I的方法, 2020-10-2, 中国, ZL201810672553 .X
3. 樊静, 张凯歌, 李双莹, 刘闯, 李想, 张霞. 疏水性低共熔溶剂涡旋辅助分散液液微萃取-高效液相色谱法检测亚硝酸根的方法, 2020-9-22, 中国, ZL201810671068.0
4. 李攻科, 张凯歌, 胡玉玲. 表面增强拉曼光谱快速检测亚硝酸根方法及其应用. 2016-2-1, 中国, ZL102998298A